Vibrational Spectra of the Azabenzenes Revisited: Anharmonic Force Fields

A. Daniel Boese and Jan M.L. Martin

Journal of Physical Chemistry A 108, 3085 - 3096 (2004)

[DOI: 10.1021/jp0369589; H. F. Schaefer III festschrift]

Preprint at arXiv.org

Supporting Information

Below are given, for each molecule (in CADPAC/SPECTRO format) the geometry in Cartesian coordinates, the quadratic force field in Cartesian coordinates, the cubic force field in normal coordinates, and the (diagonal and semidiagonal) quartic force field in normal coordinates. In addition, we provide the Lxm (mass-weighted normal coordinate) matrix and the Zeta (Coriolis coupling constant) matrix, as one or the other is required to uniquely define the phases of the normal modes.

benzene geom fcm2 fcmq3 fcmq4 lxmzeta
pyridine geom fcm2 fcmq3 fcmq4 lxmzeta
pyridazine geom fcm2 fcmq3 fcmq4 lxmzeta
pyrimidine geom fcm2 fcmq3 fcmq4 lxmzeta
pyrazine geom fcm2 fcmq3 fcmq4 lxmzeta
1,2,3-triazine geom fcm2 fcmq3 fcmq4 lxmzeta
1,2,4-triazine geom fcm2 fcmq3 fcmq4 lxmzeta
1,3,5-triazine geom fcm2 fcmq3 fcmq4 lxmzeta
s-tetrazine geom fcm2 fcmq3 fcmq4 lxmzeta

E.O.E. Comments and questions to comartin@wicc.weizmann.ac.il.