regular W1 theory SCF/AVDZ+2d SCF/AVTZ+2d1f SCF/AVQZ+2d1f H(2S) -0.499334315440 -0.499821176024 -0.499948321469 B(2P) -24.526872533718 -24.528202159578 -24.528975116825 C(3P) -37.683129527032 -37.686836739940 -37.688322855017 N(4S) -54.389870729087 -54.397609522653 -54.400224914198 O(3P) -74.790958626998 -74.806508391742 -74.811064141923 F(2P) -99.377068840448 -99.402083121383 -99.409209020628 Al(2P) -241.870533262245 -241.875309528741 -241.876509867397 Si(3P) -288.847062455374 -288.852392899356 -288.854150605903 P(4S) -340.709814214001 -340.716123552911 -340.718349317424 S(3P) -397.494333002045 -397.504068610149 -397.506734049274 Cl(2P) -459.468515522457 -459.480274460618 -459.483331599221 CCSD/AVDZ+2d CCSD/AVTZ+2d1f CCSD/AVQZ+2d1f CCSD(T)/AVDZ+2d CCSD(T)/AVTZ+2d1f H(2S) -0.499334315440 -0.499821176024 -0.499948321469 -0.499334315440 -0.499821176024 B(2P) -24.590076520119 -24.596938172270 -24.599319198039 -24.591077638855 -24.598424393228 C(3P) -37.763468530144 -37.779450383947 -37.784260914510 -37.764802894762 -37.781729057334 N(4S) -54.485548353801 -54.514112842599 -54.522355540918 -54.486848958476 -54.516714200976 O(3P) -74.923710470004 -74.975311092336 -74.991175026620 -74.925570031662 -74.978822977347 F(2P) -99.547684437094 -99.623349655724 -99.647865823412 -99.550034466038 -99.627771310924 Al(2P) -241.923103476569 -241.930408572102 -241.932366853910-241.924125785678 -241.931808177129 Si(3P) -288.919783018797 -288.931756655957 -288.934982391358-288.921422535533 -288.934589904465 P(4S) -340.799833447579 -340.819315742752 -340.824024447540-340.801778096338 -340.823531764880 S(3P) -397.616158409550 -397.653498288649 -397.662749554977-397.618873028286 -397.659078615725 Cl(2P) -459.620911633939 -459.673640076035 -459.688656987222-459.624131284833 -459.680522549155 W1' theory (minor modification of W1 theory for 2nd row) SCF/AVDZ+2d SCF/AVTZ+2d SCF/AVQZ+2d1f H(2S) -0.499334315440 -0.499821176024 -0.499948321469 B(2P) -24.526872533718 -24.528202159578 -24.528975116825 C(3P) -37.683129527032 -37.686836739940 -37.688322855017 N(4S) -54.389870729087 -54.397609522653 -54.400224914198 O(3P) -74.790958626998 -74.806508391742 -74.811064141923 F(2P) -99.377068840448 -99.402083121383 -99.409209020628 Al(2P) -241.870533262245 -241.875298713045 -241.876509867397 Si(3P) -288.847062455374 -288.852376597433 -288.854150605903 P(4S) -340.709814214001 -340.716123552910 -340.718349317424 S(3P) -397.494333002045 -397.504028817213 -397.506734049274 Cl(2P) -459.468515522457 -459.480227103764 -459.483331599221 CCSD/AVDZ+2d CCSD/AVTZ+2d CCSD/AVQZ+2d1f CCSD(T)/AVDZ+2d CCSD(T)/AVTZ+2d H(2S) -0.499334315440 -0.499821176024 -0.499948321469 -0.499334315440 -0.499821176024 B(2P) -24.590076520119 -24.596938172270 -24.599319198039 -24.591077638855 -24.598424393228 C(3P) -37.763468530144 -37.779450383947 -37.784260914510 -37.764802894762 -37.781729057334 N(4S) -54.485548353801 -54.514112842599 -54.522355540918 -54.486848958476 -54.516714200976 O(3P) -74.923710470004 -74.975311092336 -74.991175026620 -74.925570031662 -74.978822977347 F(2P) -99.547684437094 -99.623349655724 -99.647865823412 -99.550034466038 -99.627771310924 Al(2P) -241.923103476569 -241.930251395536 -241.932366853916 -241.924125785678 -241.931634584237 Si(3P) -288.919783018797 -288.931403286032 -288.934982391358 -288.921422535533 -288.934178575814 P(4S) -340.799833447579 -340.818728849980 -340.824024447540 -340.801778096338 -340.822826839536 S(3P) -397.616158409550 -397.652056769181 -397.662749554977 -397.618873028286 -397.657442915292 Cl(2P) -459.620911633939 -459.671583982142 -459.688656987222 -459.624131284833 -459.678213127230 regular W2 theory SCF/AVTZ+2d1f SCF/AVQZ+2d1f SCF/AV5Z+2d1f H(2S) -0.499821176024 -0.499948321469 -0.499994784584 B(2P) -24.528202159578 -24.528975116825 -24.529111652159 C(3P) -37.686836739940 -37.688322855017 -37.688645647085 N(4S) -54.397609522653 -54.400224914198 -54.400855630945 O(3P) -74.806508391742 -74.811064141923 -74.812257557783 F(2P) -99.402083121383 -99.409209020628 -99.411197055583 Al(2P) -241.875309528741 -241.876509867397 -241.876794501233 Si(3P) -288.852392899356 -288.854150605903 -288.854463012627 P(4S) -340.716123552911 -340.718349317423 -340.718681727286 S(3P) -397.504068610149 -397.506734049274 -397.507151029803 Cl(2P) -459.480274460618 -459.483331599221 -459.483818017342 CCSD/AVTZ+2d1f CCSD/AVQZ+2d1f CCSD/AV5Z+2d1f CCSD(T)/AVTZ+2d1f CCSD(T)/AVQZ+2d1f H(2S) -0.499821176024 -0.499948321469 -0.499994784584 -0.499821176024 -0.499948321469 B(2P) -24.596938172270 -24.599319197992 -24.599933556500 -24.598424393228 -24.600921236929 C(3P) -37.779450383947 -37.784260914525 -37.785678151594 -37.781729057334 -37.786774592002 N(4S) -54.514112842599 -54.522355540909 -54.524933545600 -54.516714200976 -54.525299667961 O(3P) -74.975311092336 -74.991175026573 -74.996468121838 -74.978822977347 -74.995132374407 F(2P) -99.623349655724 -99.647865823389 -99.656371164184 -99.627771310924 -99.652845103807 Al(2P) -241.930408572102 -241.932366853918 -241.933029478430 -241.931808177129 -241.933860606923 Si(3P) -288.931756655957 -288.934982391358 -288.935970240294 -288.934589904465 -288.938060957046 P(4S) -340.819315742752 -340.824024447540 -340.825547492727 -340.823531764880 -340.828692548559 S(3P) -397.653498288649 -397.662749554900 -397.665695933006 -397.659078615725 -397.668963868395 Cl(2P) -459.673640076035 -459.688656987124 -459.693296366676 -459.680522549155 -459.696374085874